Groundstate dispersion interaction between pi-conjugated polymers.
نویسندگان
چکیده
The line-dipole approximation is used to investigate the scaling of the groundstate dispersion interaction, EW, between parallel conjugated polymers of length L and transverse separation D. Both a second-order perturbation theory calculation using the Mott-Wannier exciton model of excited states and a semiclassical analysis of distributed dipoles indicate that at L approximately D there is a crossover from the point-dipole approximation result of EW approximately L2/D6 for L<>D.
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ورودعنوان ژورنال:
- The Journal of chemical physics
دوره 128 3 شماره
صفحات -
تاریخ انتشار 2008